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- W173663849 abstract "Present-day ground water models used to explain the development of cavernous porosity within Guadalupian rocks in southeast New Mexico fail for one or more of the following reasons: 1) the chemical relations in the model are incorrect from a thermodynamic standpoint; 2) the three dimensional geometry of the cavernous porosity is not explained in the model; 3) the source of the sulfates in the model is insufficient volumetrically; 4) the stratigraphic relations invoked by the model are incorrect; 5) the hydrologic aspects of the model are incorrect. The authors believe that the present models may be modified to explain the development of cavernous porosity in these rocks as follows. Hydrogen sulfide gas is produced by bacterial reduction of gypsum within or adjacent to the Castile Formation. The gas then ascends through saline waters until reaching the fresh water-saline water interface where the H/sub 2/S is oxidized into sulfuric acid, which in turn dissolves the limestone. Large rooms are excavated in the fresh groundwater zone. Simultaneously, hydronium ions diffuse downward into the saline water, and after overcoming the buffering effect of the water, dissolve the randomly spaced and interconnected voids called boneyard. The spatial position and size of large rooms aremore » controlled by the path of the hydrogen sulfide plume, the size and shape of the plume, thickness of the freshwater lens, persistence of the plume, and the position of the fresh-saline interface.« less" @default.
- W173663849 created "2016-06-24" @default.
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- W173663849 date "1985-01-01" @default.
- W173663849 modified "2023-09-28" @default.
- W173663849 title "Model for the development of cavernous porosity in Guadalupian rocks in southeast New Mexico" @default.
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