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- W1738008524 abstract "The synthesis and characterization of two bimetallic, cationic low-valent gallium-cryptand[2.2.2] complexes is reported. The reaction of cryptand[2.2.2] with Ga2Cl4 gave two different cations, [Ga3Cl4 (crypt-222)](+) (1) or [Ga2Cl2 (crypt-222)](2+) (2), depending on whether or not trimethylsilyl triflate (Me3SiOTf) was added as a co-reagent. Complexes 1 and 2 are the first examples of bimetallic cryptand[2.2.2] complexes, as well as the first low-valent gallium-cryptand[2.2.2] complexes. Computational methods were used to evaluate the bonding in the gallium cores." @default.
- W1738008524 created "2016-06-24" @default.
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- W1738008524 date "2015-06-03" @default.
- W1738008524 modified "2023-10-10" @default.
- W1738008524 title "Synthesis and Characterization of Cationic Low-Valent Gallium Complexes of Cryptand[2.2.2]" @default.
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- W1738008524 doi "https://doi.org/10.1002/chem.201501345" @default.
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