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- W1738234301 abstract "Turquoise crystals of the title salt, propylammonium di-μ-thio-1:2κ4S-dithio-2κ2S-tris(2-aminoethyl)amine-1κ4N-antimony(V)nickel(II), (C3H10N)[NiSbS4(C6H18N4)] or [PAH][Ni(tren)SbS4] [where tren is tris(2-aminoethyl)amine and PA is propylamine], were synthesized under solvothermal conditions by reacting [Ni(tren)2]Cl2, Sb and S in a solution of PA. The NiII ion is octahedrally surrounded by four N atoms of the tetradentate tren molecule and by two S atoms of the tetrahedral [SbVS4]3− anion, thus forming the anionic [Ni(tren)SbS4]− part of the compound. Charge balance is achieved through the PAH+ cation. An extended intermolecular hydrogen-bonding network is observed between the anion and the cation." @default.
- W1738234301 created "2016-06-24" @default.
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- W1738234301 date "2002-10-22" @default.
- W1738234301 modified "2023-09-27" @default.
- W1738234301 title "The new thioantimonate(V) (C<sub>3</sub>H<sub>10</sub>N)[NiSbS<sub>4</sub>(C<sub>6</sub>H<sub>18</sub>N<sub>4</sub>)]" @default.
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- W1738234301 doi "https://doi.org/10.1107/s0108270102017754" @default.
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