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- W1743105895 abstract "Nonstoichiometric nickel oxide (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M1><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>) has been deposited as thin film utilizing indium-doped tin oxide as transparent and electrically conductive substrate. Spray deposition of a suspension of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M2><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>nanoparticles in alcoholic medium allowed the preparation of uniform<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M3><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>coatings. Sintering of the coatings was conducted at temperatures below 500°C for few minutes. This scalable procedure allowed the attainment of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M4><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>films with mesoporous morphology and reticulated structure. The electrochemical characterization showed that<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M5><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>electrodes possess large surface area (about 1000 times larger than their geometrical area). Due to the openness of the<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M6><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>morphology, the underlying conductive substrate can be contacted by the electrolyte and undergo redox processes within the potential range in which<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M7><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>is electroactive. This requires careful control of the conditions of polarization in order to prevent the simultaneous occurrence of reduction/oxidation processes in both components of the multilayered electrode. The combination of the open structure with optical transparency and elevated electroactivity in organic electrolytes motivated us to analyze the potential of the spray-deposited<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M8><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi><mml:mi mathvariant=normal>i</mml:mi><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>films as semiconducting cathodes of dye-sensitized solar cells of p-type when erythrosine B was the sensitizer." @default.
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- W1743105895 title "Electrochemical Characterization of Nanoporous Nickel Oxide Thin Films Spray-Deposited onto Indium-Doped Tin Oxide for Solar Conversion Scopes" @default.
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