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- W174697958 abstract "The structural features of the ammoniated fulleride (NH3)K3C60 are studied by neutron and synchrotron X-ray powder diffraction at low temperature and high pressure, respectively. Below 150 K the system adopts an orthorhombic structure in space group Fddd. Rietveld refinements led to the determination of the exact orientation and geometry of both the C60 units (antiferrorotative ordering) and the ammonia molecules in the pseudo octahedral sites (antiferroelectric ordering). We also performed synchrotron X-ray powder diffraction measurements at pressures between ambient and 3.9 GPa. Near ∼1 GPa, (NH3)K3C60 undergoes a structural phase transition from orthorhombic Fmmm (isostructural with the ambient pressure high temperature phase) to orthorhombic Fddd (isostructural with the ambient pressure low temperature phase)." @default.
- W174697958 created "2016-06-24" @default.
- W174697958 creator A5023085816 @default.
- W174697958 date "2000-01-01" @default.
- W174697958 modified "2023-09-25" @default.
- W174697958 title "Structural studies of (NH[sub 3])K[sub 3]C[sub 60] at ambient and high pressure" @default.
- W174697958 doi "https://doi.org/10.1063/1.1342463" @default.
- W174697958 hasPublicationYear "2000" @default.
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