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- W1750275816 abstract "A series of 5 randomly designed in-house cyclometalated Ir(III) complexes were examined for their application in G-pentaplex probes and the proof-of-principle concept in G-pentaplex-based Cs(+) ions detection. The G-pentaplex-forming sequence (DNA1, 5'-T(iG)4T-3', where iG=isoguanine) is present in single strand DNA form ab initio, however, the addition of Cs(+) ions lead to formation of the intermolecular G-pentaplex structure which is identified by the novel Ir(III) complex 1 afterward and produce an enhanced luminescence signal for Cs(+) ions monitoring. To the best of our knowledge, this is the first G-pentaplex probe and also the first G-pentaplex-based label-free detection platform for Cs(+) ions reported in the literature. The monitoring of spiked Cs(+) ions in natural water samples demonstrates the potential application and technical sound of this proof-of-principle concept sensing platform." @default.
- W1750275816 created "2016-06-24" @default.
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- W1750275816 date "2016-03-01" @default.
- W1750275816 modified "2023-10-13" @default.
- W1750275816 title "A G-pentaplex-based assay for Cs + ions in aqueous solution using a luminescent Ir(III) complex" @default.
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- W1750275816 doi "https://doi.org/10.1016/j.bios.2015.10.026" @default.
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