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- W175027879 abstract "Publisher Summary This chapter focuses on the synthesis of diphenyl-alkanes, alkenes, and alkynes and their derivatives. The Friedel–Crafts reaction is one of the most prevalent methods for the preparation of 1, 1-diphenylalkanes and their derivatives. The advantages of perfluorooctane sulfonic acid as a catalyst are described. A facile preparation of 3-aryl-3-(3, 4-dimethoxyphenyl)propionic acids relies on the Lewis acid-mediated alkylation of veratrol with ethyl cinnamates. These products are useful intermediates in the synthesis of various isoquinoline derivatives. Addition of aryl lithiums to aromatic aldehydes and ketones is a common strategy for the synthesis of 1, 1-diphenylalkanols. A 1, 1-diarylamine is the product of the reaction between an aryl lithium and an imine derived from benzaldehyde. Treatment with DDQ effects oxidation to the corresponding imine. Transformation of a benzylic carbonyl group to the corresponding benzylic halide can conveniently be achieved by reduction with lithium aluminium hydride at low temperature, followed by quenching with a hydrogen halide." @default.
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- W175027879 date "1991-01-01" @default.
- W175027879 modified "2023-09-27" @default.
- W175027879 title "Diphenyl-alkanes,-alkenes, and -alkynes, their derivatives and oxidation products" @default.
- W175027879 doi "https://doi.org/10.1016/b978-044453347-0.50122-1" @default.
- W175027879 hasPublicationYear "1991" @default.
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