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- W1752668654 abstract "Abstract Two novel complexes, tetramer [Co 4 L 8 ] ( 1 ) and dimer [Cu 2 L 4 ] ( 2 ) (L = ( E )-2-(2-fluoro-4-methoxystyryl)-8-hydroxyquinoline), were synthesized and characterized by single-crystal X-ray diffractions, powder X-ray diffractions (PXRD), thermal-gravimetric analyses (TGA), infrared radiation (IR) and elemental analyses (EA). In the solid state, both of their supramolecular structures were constructed by C H⋯F dispersive interactions. In addition, the differences in the structure between 1 and 2 have been discussed: supramolecular structures of complex 1 were constructed by C H⋯O and C F⋯π intermolecular interactions, however, supramolecular structures of complex 2 were mainly constructed by C F⋯F C intermolecular interactions and π⋯π stacking. Obviously, the C F group which takes part in attractive interactions with other molecules is important to construct supramolecular structures and plays different roles in the two novel complexes. Magnetic analysis of 1 indicates that the antiferromagnetic coupling dominates the magnetic properties." @default.
- W1752668654 created "2016-06-24" @default.
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- W1752668654 date "2015-12-01" @default.
- W1752668654 modified "2023-10-17" @default.
- W1752668654 title "The geometry of intermolecular interactions in fluorine-containing 8-hydroxyquinoline cobalt(II) and copper(II) complexes: Synthesis, crystal structure and characterization" @default.
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- W1752668654 doi "https://doi.org/10.1016/j.jfluchem.2015.09.006" @default.
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