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• W1753082866 abstract "N-doped TiO2-B nanowires are prepared by the solvothermal method using TiN nanoparticles as the starting material. X-ray photoelectron spectroscopy shows that the N dopants preferentially occupy the interstitial sites of TiO2-B up to a content of ∼0.55 at%. Above this critical value, the N dopants will substitute the oxygen atoms which improve the electronic conductivity of TiO2-B. The maximum proportion of substituted-N in the TiO2-B nanowires is ∼1.3 at%. Raman scattering shows that the substituted-N strengthens the Ti(1)-O1-Ti(2) and O1-Ti(1)-O3 bonds of TiO2-B. This improves the stability of the corresponding local structures, thus reducing the distortion of the Li(+) diffusion channel along the b-axis of TiO2-B. As a result, the substituted-N has more of an impact on the electrochemical properties of TiO2-B than the interstitial-N does. The TiO2-B nanowires containing substituted-N dopants exhibit a remarkably enhanced electrochemical performance compared to pure TiO2-B. They show a discharge capacity of 153 mA h g(-1) at the 20 C rate with a capacity retention of 76% after 1000 cycles. In addition, they can deliver a discharge capacity of 100 mA h g(-1) at an ultra-high rate of 100 C, indicating their great potential in high power lithium ion batteries." @default.
• W1753082866 created "2016-06-24" @default.
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• W1753082866 date "2015-01-01" @default.
• W1753082866 modified "2023-10-06" @default.
• W1753082866 title "Improved electrochemical performance of nitrogen doped TiO₂-B nanowires as anode materials for Li-ion batteries" @default.
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• W1753082866 doi "https://doi.org/10.1039/c5nr02457a" @default.
• W1753082866 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26132786" @default.
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