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• W1761218593 abstract "Although the cyclo-P6 complex [(Cp*Mo)2 (μ,η(6) :η(6) -P6 )] (1) was reported 30 years ago, little is known about its chemistry. Herein, we report a high-yielding synthesis of 1, the complex 2, which contains an unprecedented cyclo-P10 ligand, and the reactivity of 1 towards the naked cations Cu(+) , Ag(+) , and Tl(+) . Besides the formation of the single oxidation products 3 a,b which have a bisallylic distorted cyclo-P6 middle deck, the [M(1)2 ](+) complexes are described which show distorted square-planar (M=Cu(4 a), Ag(4 b)) or distorted tetrahedral coordinated (M=Cu(5)) M(+) cations. The choice of solvent enabled control over the reaction outcome for Cu(+) , as proved by powder XRD and supported by DFT calculations. The reaction with Tl(+) affords a layered two-dimensional coordination network in the solid state." @default.
• W1761218593 created "2016-06-24" @default.
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• W1761218593 date "2015-09-04" @default.
• W1761218593 modified "2023-10-07" @default.
• W1761218593 title "Redox and Coordination Behavior of the Hexaphosphabenzene Ligand in [(Cp*Mo) ₂ (μ,η ⁶ :η ⁶ ‐P ₆ )] Towards the “Naked” Cations Cu ⁺ , Ag ⁺ , and Tl ⁺" @default.
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• W1761218593 doi "https://doi.org/10.1002/anie.201506362" @default.
• W1761218593 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4675074" @default.
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