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- W1771546996 abstract "Thallium cation complexation by calix[4]tubes has been investigated by a combination of 205Tl, 1H NMR and ES MS demonstrating the solution formation of a dithallium complex in which the cations are held in the calix[4]arene cavities. In addition, the structure of the complex has been determined in the solid state revealing the cations to be held exclusively by π-cation interactions. Furthermore, this crystal structure has been used as the basis for molecular dynamics simulations to confirm that binding of the smaller K+ cation in the calix[4]tube cryptand like array occurs via the axial route featuring a π-cation intermediate." @default.
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- W1771546996 date "2003-01-16" @default.
- W1771546996 modified "2023-09-27" @default.
- W1771546996 title "Thallium π-Cation Complexation by Calix[4]tubes: <sup>205</sup>Tl NMR and X-ray Evidence" @default.
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- W1771546996 doi "https://doi.org/10.1021/ic025884x" @default.
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