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- W1774001803 abstract "Publisher SummaryAn important breakthrough in the search for heat and fluid resistant elastomers to meet the demands of the aerospace industry was the discovery of DuPont's Viton® A in the mid-1950s. Its thermal stability was considerably lower than that of the raw elastomer owing to the nature of the curing reactions and the relative instability of the hydrocarbon-type crosslinks. Thus, improved cross-linking techniques were required. One method under consideration at the University of Manchester Institute of Science and Technology (UMIST) was to synthesize linear polymer chains incorporating units containing a pendant thermally-labile functional group (X). Kalathil C. Eapen undertook a postdoctoral assignment at the UMIST in 1969. As the project on the “self-curing” fluoroelastomers did not produce the hoped-for results, he decided to abandon it and start a new one. The first perfluorinated nitroxide to be isolated was the monooxyl (CF3)2NO·, known at UMIST as the “magic radical.” His work at Wright–Patterson Air Force Base (WPAFB), Ohio covered a variety of topics, including studies on both fluorinated and nonfluorinated materials." @default.
- W1774001803 created "2016-06-24" @default.
- W1774001803 creator A5038676864 @default.
- W1774001803 date "2000-01-01" @default.
- W1774001803 modified "2023-09-27" @default.
- W1774001803 title "Fluoropolymers, stable nitroxides and perfluoroalkylation" @default.
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