FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1775850196> ?p ?o ?g. }

• W1775850196 endingPage "237" @default.
• W1775850196 startingPage "231" @default.
• W1775850196 abstract "The high solubility in acidic solutions of N-bis(N′,N′-diethyl-2-aminoethyl)-4-aminomethylphenyl-diphenylphosphine (N3P) make it a suitable candidate for study and comparison to the more commonly studied trisulfonated triphenylphosphine (TPPTS) ligand in the palladium catalysed aqueous hydrocarboxylation reaction. The catalyst employing N3P shows an inverted regioselectivity compared to the TPPTS system. Non-coordinating anions give the best results in terms of activity and stability of the catalyst. Due to N3P amphiphilic character and contrary to sulfonated phosphines reaction, it is possible to recycle the catalyst, both by extracting the substrate and by extracting the catalyst into an organic solvent. The hydrocarboxylation of styrene, 1-octene and 4-penteneoic acid demonstrates that the reaction rate is strongly dependent on the solubility of the substrates. Using the water-soluble 3-buten-1-ol as substrate, two palladium zerovalent complexes, two palladium hydrides, one acyl and one alkyl complexes were identified by means of NMR and IR." @default.
• W1775850196 created "2016-06-24" @default.
• W1775850196 creator A5014541444 @default.
• W1775850196 creator A5061680091 @default.
• W1775850196 creator A5083420264 @default.
• W1775850196 date "2006-11-01" @default.
• W1775850196 modified "2023-10-05" @default.
• W1775850196 title "Hydrocarboxylation of olefins using an amphiphilic palladium catalyst, activity and recycling properties" @default.
• W1775850196 cites W1484105415 @default.
• W1775850196 cites W1560219421 @default.
• W1775850196 cites W1988574239 @default.
• W1775850196 cites W1996837362 @default.
• W1775850196 cites W2001817660 @default.
• W1775850196 cites W2004668828 @default.
• W1775850196 cites W2004885353 @default.
• W1775850196 cites W2015026035 @default.
• W1775850196 cites W2015358180 @default.
• W1775850196 cites W2026639147 @default.
• W1775850196 cites W2029330262 @default.
• W1775850196 cites W2052926627 @default.
• W1775850196 cites W2075260104 @default.
• W1775850196 cites W2083104995 @default.
• W1775850196 cites W2095137828 @default.
• W1775850196 cites W2098359037 @default.
• W1775850196 cites W2101471628 @default.
• W1775850196 cites W2120173290 @default.
• W1775850196 cites W2164515734 @default.
• W1775850196 cites W2952505148 @default.
• W1775850196 cites W54926311 @default.
• W1775850196 doi "https://doi.org/10.1016/j.molcata.2006.06.036" @default.
• W1775850196 hasPublicationYear "2006" @default.
• W1775850196 type Work @default.
• W1775850196 sameAs 1775850196 @default.
• W1775850196 citedByCount "14" @default.
• W1775850196 countsByYear W17758501962013 @default.
• W1775850196 countsByYear W17758501962015 @default.
• W1775850196 countsByYear W17758501962017 @default.
• W1775850196 countsByYear W17758501962019 @default.
• W1775850196 countsByYear W17758501962021 @default.
• W1775850196 crossrefType "journal-article" @default.
• W1775850196 hasAuthorship W1775850196A5014541444 @default.
• W1775850196 hasAuthorship W1775850196A5061680091 @default.
• W1775850196 hasAuthorship W1775850196A5083420264 @default.
• W1775850196 hasConcept C100805817 @default.
• W1775850196 hasConcept C116569031 @default.
• W1775850196 hasConcept C155574463 @default.
• W1775850196 hasConcept C15920480 @default.
• W1775850196 hasConcept C161790260 @default.
• W1775850196 hasConcept C170493617 @default.
• W1775850196 hasConcept C178790620 @default.
• W1775850196 hasConcept C185592680 @default.
• W1775850196 hasConcept C188027245 @default.
• W1775850196 hasConcept C2776416708 @default.
• W1775850196 hasConcept C2777247709 @default.
• W1775850196 hasConcept C2777716191 @default.
• W1775850196 hasConcept C2779211555 @default.
• W1775850196 hasConcept C502130503 @default.
• W1775850196 hasConcept C521398313 @default.
• W1775850196 hasConcept C521977710 @default.
• W1775850196 hasConcept C55493867 @default.
• W1775850196 hasConcept C59759590 @default.
• W1775850196 hasConcept C67407626 @default.
• W1775850196 hasConceptScore W1775850196C100805817 @default.
• W1775850196 hasConceptScore W1775850196C116569031 @default.
• W1775850196 hasConceptScore W1775850196C155574463 @default.
• W1775850196 hasConceptScore W1775850196C15920480 @default.
• W1775850196 hasConceptScore W1775850196C161790260 @default.
• W1775850196 hasConceptScore W1775850196C170493617 @default.
• W1775850196 hasConceptScore W1775850196C178790620 @default.
• W1775850196 hasConceptScore W1775850196C185592680 @default.
• W1775850196 hasConceptScore W1775850196C188027245 @default.
• W1775850196 hasConceptScore W1775850196C2776416708 @default.
• W1775850196 hasConceptScore W1775850196C2777247709 @default.
• W1775850196 hasConceptScore W1775850196C2777716191 @default.
• W1775850196 hasConceptScore W1775850196C2779211555 @default.
• W1775850196 hasConceptScore W1775850196C502130503 @default.
• W1775850196 hasConceptScore W1775850196C521398313 @default.
• W1775850196 hasConceptScore W1775850196C521977710 @default.
• W1775850196 hasConceptScore W1775850196C55493867 @default.
• W1775850196 hasConceptScore W1775850196C59759590 @default.
• W1775850196 hasConceptScore W1775850196C67407626 @default.
• W1775850196 hasIssue "1-2" @default.
• W1775850196 hasLocation W17758501961 @default.
• W1775850196 hasOpenAccess W1775850196 @default.
• W1775850196 hasPrimaryLocation W17758501961 @default.
• W1775850196 hasRelatedWork W1552794442 @default.
• W1775850196 hasRelatedWork W1990622120 @default.
• W1775850196 hasRelatedWork W1992730209 @default.
• W1775850196 hasRelatedWork W1999313643 @default.
• W1775850196 hasRelatedWork W2011543742 @default.
• W1775850196 hasRelatedWork W2016989953 @default.
• W1775850196 hasRelatedWork W2034657744 @default.
• W1775850196 hasRelatedWork W2089171628 @default.
• W1775850196 hasRelatedWork W2091407852 @default.
• W1775850196 hasRelatedWork W2952829611 @default.
• W1775850196 hasVolume "259" @default.
• W1775850196 isParatext "false" @default.
• W1775850196 isRetracted "false" @default.

• next