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- W177849770 abstract "A number of complex uranyl compounds containing homogeneous cyclic addends were studied. The existence of three genetic families of complex uranyl corapounds was shown. Complex uranyl compounds with heterogeneous cyclic substitutes were synthesized and studied on the basis of the displacing capacity of the addends under investigation. Mixed oxalate complex uranyl compounds containing noncyclic addends were synthesized and studied, such as ureate, acetate, and thiocyanate groups. The investigations conducted showed that uranyl ion, in the compounds studied has the coordination number six. The analyzed addends forming a cycle according to the power of their reciprocal displacing capacity are aligned in series. Carbonate uranyl compounds are the only exceptions from L. A. Chugayev's rule of cycles in the chemistry of complex compounds, exceptions which are caused by the nature of both the formation of complexes and of the addends. (auth)" @default.
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- W177849770 date "1959-10-31" @default.
- W177849770 modified "2023-09-27" @default.
- W177849770 title "ON THE STRUCTURE OF COMPLEX URANYL COMPOUNDS" @default.
- W177849770 hasPublicationYear "1959" @default.
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