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- W1779577061 abstract "Abstract The conformational conversion between an extended and a helical conformation of PTT chains during uniaxially cold drawing with different draw rates at temperatures below and above glass transition temperature (Tg) was investigated by time-resolved polarized IR analysis. When the draw rate ( γ ˙ ) is faster than the retraction rate (1/τb) of chain segments, the drawing-induced extended conformation can be found. On the contrary, polymer chains can adjust to form a helical conformation. Besides, the conformation fraction, segmental orientation, inter-molecular interactions, relative mobility of the flexible and rigid segments of PTT chains and cold crystallization behavior were discussed in detail for clarifying the micro-structural changes during drawing process, and we found that the segmental orientation and the conformational changes occurred simultaneously when T Tg." @default.
- W1779577061 created "2016-06-24" @default.
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- W1779577061 date "2015-11-01" @default.
- W1779577061 modified "2023-10-18" @default.
- W1779577061 title "Studies on conformational changes of poly(trimethylene terephthalate) chains during uniaxially cold drawing using time-resolved polarized infrared analysis" @default.
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- W1779577061 doi "https://doi.org/10.1016/j.polymer.2015.09.064" @default.
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