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- W1781434663 abstract "Abstract We discussed the formation of platinum hierarchical micro/nanostructure by varying the synthesis time using two amine derivatives, e.g. Monoethanolamine (MEA) and Diethanolamine (DEA) as the reducing agent. This work shows that the amine derivatives play a crucial role in controlling the reducing rate as Pt synthesised with DEA exhibited the fastest growth process whilst the synthesis time influences the development of Pt anisotropic structures. With a shorter synthesis time of 5 h, both particles synthesised using MEA and DEA exhibit small flower-like structures, while a larger network of flower-like microstructure was established at 9 h. The optimum condition for Pt assisted MEA and DEA is 7th hour for MEA and 5th hour for DEA. The particles produced using DEA during the 5th hour of synthesis time had a large electrochemical surface area (5.90 cm −2 g −1 ), high catalytic activity and greater tolerance against CO adsorption. For particles synthesised with MEA, at the 7th hour, the reaction produces bigger flower-like particles comprised of collective triangular petals having 4.88 cm −2 g −1 electrochemical surface areas and exhibit greater stability at a longer period." @default.
- W1781434663 created "2016-06-24" @default.
- W1781434663 creator A5069217807 @default.
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- W1781434663 date "2015-11-01" @default.
- W1781434663 modified "2023-09-29" @default.
- W1781434663 title "The role of amine derivatives in the formation of hierarchical Pt micro/nanostructures" @default.
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- W1781434663 doi "https://doi.org/10.1016/j.matchemphys.2015.10.028" @default.
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