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- W1781481775 abstract "Biaryls are a common motif in both natural and synthetic chemicals. Several methods have recently been reported for the preparation of these compounds using direct arylation catalyzed by iron, other base metals, or transition-metal-free systems. To date, these methods have all required inert and/or forcing conditions, which limited their application in routine organic synthesis. In this article we report a protocol for direct arylation using a convenient FeCl3/1,10-phenanthroline system as precatalyst. The reaction proceeds under mild conditions (100 °C), under air, and with non-distilled solvent." @default.
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- W1781481775 date "2014-05-12" @default.
- W1781481775 modified "2023-10-14" @default.
- W1781481775 title "Iron-Mediated Direct Arylation of Unactivated Arenes in Air" @default.
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- W1781481775 doi "https://doi.org/10.1002/ejoc.201301620" @default.
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