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• W1782327604 abstract "A new strategy is presented for achieving selective heteronuclear polarization transfers from half-integer quadrupolar spins in magic-angle spinning (MAS) NMR. By combining cross-polarization with a recently introduced RAPT pulse sequence that selectively excites the signal of a half-integer quadrupolar nucleus based on its quadrupolar coupling constant magnitude, we demonstrate that hetero-nuclei in its close proximity may be selectively excited. Selective 23Na → 1H polarization transfers are demonstrated in Na2MoO4·2H2O, Na2HPO4·2H2O and a mixture of NaHCO3 and Na2HPO4·2H2O." @default.
• W1782327604 created "2016-06-24" @default.
• W1782327604 creator A5041549221 @default.
• W1782327604 date "2006-01-01" @default.
• W1782327604 modified "2023-09-25" @default.
• W1782327604 title "Quadrupolar coupling selective cross-polarization in solid state NMR" @default.
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• W1782327604 doi "https://doi.org/10.1039/b600757k" @default.
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