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- W1788292461 abstract "Abstract This work reports the synthesis of a new matrix material (graphene-supported NiCl 2 and CoCl 2 nanoparticles) for loading ammonia borane (AB) and investigates their catalysis effect for dehydrogenation properties. The NiCl 2 and CoCl 2 nanoparticles are obtained with the size around 3–10 nm and dispersed uniformly on the surface of graphene, which exhibit enhanced catalysis effect for the dehydrogenation of AB. The AB@NiCl 2 /CoCl 2 -graphene system, obtained via loading AB on the NiCl 2 /CoCl 2 -graphene scaffold, shows much lower onset dehydrogenation temperature of 60–90 °C and effective suppression of those byproducts such as ammonia, diborane and borazine formations compared with pristine AB. Meanwhile, the activation energy of AB@NiCl 2 /CoCl 2 -graphene has been calculated to explore the improvement of dehydrogenation kinetics of AB under the existence of graphene-supported NiCl 2 or CoCl 2 nanoparticles." @default.
- W1788292461 created "2016-06-24" @default.
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- W1788292461 date "2015-12-01" @default.
- W1788292461 modified "2023-10-08" @default.
- W1788292461 title "Graphene-supported nickel chloride and cobalt chloride nanoparticles as highly efficient catalysts for dehydrogenation of ammonia borane" @default.
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- W1788292461 doi "https://doi.org/10.1016/j.ijhydene.2015.09.088" @default.
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