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- W1789788992 abstract "New FeII guest-dependent spin crossover (SCO) coordination polymers, {FeII4-(3-pentyl)pyridine2[AuI(CN)2]2·(guest)}n (guest = 4-(3-pentyl)pyridine (1a), non-guest (1b)) has been prepared and investigated by magnetic measurement and X-ray structure analysis. The adsorbed state has a two-step transition with a broad temperature-range intermediate state, whereas the desorbed state has a one-step transition. 1b is maintained HS state down to around 200 K. Below this temperature, 1b displays nearly 50% one-step transition. The first transition of 1a starts below ca. 280 K and almost completes at ca. 210 K. Below around 120 K, second transition starts and completes around 65 K, which 50% of high-spin is remaining. Interlayer spaces between two dimensional sheets are greater than other similar 2D Hoffman-like clathrates." @default.
- W1789788992 created "2016-06-24" @default.
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- W1789788992 date "2016-01-01" @default.
- W1789788992 modified "2023-09-26" @default.
- W1789788992 title "Guest-dependent spin transition with long range intermediate state for 2-dimensional Hofmann-like coordination polymer" @default.
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- W1789788992 doi "https://doi.org/10.1016/j.ica.2015.10.011" @default.
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