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• W1792639671 startingPage "4285" @default.
• W1792639671 abstract "The structural phase transitions of the LiK 0.50 Rb 0.50 SO 4 mixed crystal were investigated by Raman spectroscopy and neutron powder diffraction up to 800 K. The results show two first order structural transitions, quite analogous to the transitions in LiKSO 4 . Raman spectra and diffraction profiles were compatible with average symmetries C 3v 4 , C 6 6 and D 2h 16 for the three observed phases, with increasing temperature. The transitions, both reconstructive, are smeared over large temperature intervals, leading to the coexistence of Raman bands and neutron peaks of the different phases and to an anomalous behavior of the lattice parameters into these intervals. In the hexagonal phase, the cell volume presents a hysteretic behavior depending on the sample thermal history. Raman spectra of the orthorhombic phase shows the high rotational disorder of the SO 4 ions, associated with the high Li positional disorder in this high conducting phase." @default.
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• W1792639671 date "1998-12-15" @default.
• W1792639671 modified "2023-09-26" @default.
• W1792639671 title "The Structural Phase Transitions in LiK0.50Rb0.50SO4Mixed Crystal" @default.
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• W1792639671 doi "https://doi.org/10.1143/jpsj.67.4285" @default.
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