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• W17941457 abstract "The fundamental processes that control the amount of water sorbed by impure plutonium-containing materials after calcination are reviewed. Of particular interest is the amount of and rate of moisture sorption at 1000 PPMv (parts-per-million vapor; -3% RH at 25 'C) and 10,000 PPMv (32% RH at 25 'C). Pure plutonium oxide powders will remain below the 0.5 wt% criterion for packaging in the DOE 3013 Standard at both water vapor concentrations [I]. Deliquescent salts that have been observed in calcined materials by DOES Materials Identification and Surveillance (MIS) program will exceed the 0.5 wt% criterion at 10,000 PPMv and will meet that standard at 1,000 PPMv. Hydrated salts will exceed the 0.5 wt% criterion at all technologically achievable water vapor concentrations if allowed to reach equilibrium. Controlling the moisture availability by controlling the atmospheric content at 1000 PPM' and limiting the access to atmospheric moisture after stabilization through the use of a properly configured stabilization boat will minimize moisture uptake by these materials." @default.
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• W17941457 date "2002-01-01" @default.
• W17941457 modified "2023-09-26" @default.
• W17941457 title "Water sorption mechanisms for MIS materials." @default.
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