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- W17977470 abstract "The effect of polar factors on the relative nucleophilicity of the oxygen and carbon reaction carriers in the alkali-metal derivatives of 2-(X-benzoyl)acetonitriles, 2-(X-benzoyl)propionitriles, and 2-(X-phenyl)acetylacetonitriles was investigated. During methylation with methyl iodide and methyl p-toluenesulfonate in DMFA the ratio of the C- and O-methylation products for all the investigated compounds decreases with increase in the accepting power of the substituent X. It was shown that the sensitivity of the C-reaction center to the effect of the substituent X is greater than that of the O-center." @default.
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- W17977470 date "1988-09-10" @default.
- W17977470 modified "2023-09-24" @default.
- W17977470 title "Mesomeric anions. X. Methylation of alkali-metal derivatives of some 1,3-ketonitriles" @default.
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