FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1798356176> ?p ?o ?g. }

• W1798356176 endingPage "4703" @default.
• W1798356176 startingPage "4700" @default.
• W1798356176 abstract "The carbonyl cluster [Ir4(CO)11(SnX3)]− [X = Cl, (1a) or Br (1b)] can be formed in good yield by insertion of SnX2 in the Ir–Br bond of [Ir4(CO)11Br]− or, much less efficiently, by substitution of bromine with [SnCl3]−, in THF at room temperature. The disubstituted cluster [Ir4(CO)10(SnCl3)2]2− (2) was obtained in 50% yields by double substitution on [Ir4(CO)11Br]−, in THF at 60 °C, whereas [Ir6(CO)15(SnCl3)]− (3) can be prepared by carbonyl substitution of the homoleptic complex [Ir6(CO)16] with an excess of [SnCl3]− in refluxing THF. In the three compounds, the SnCl3 units act as a one electron donor, displaying terminal (in 2), edge-bridging (in 1 and 2) and face-bridging (in 3) coordination. In keeping with a reduced bond order, the Ir–Sn bond distances increase in the series, being 2.584(1) Å for a terminal group; 2.72 Å for edge-bringing units and 2.78 Å for the face-bridging SnCl3. Regardless of the coordination mode, the geometry of the three chlorine atoms is always pyramidal, with Cl–Sn–Cl angles close to 90° and Sn–Cl bond distances close to 2.42 Å. Tin is always symmetrically bridging, with Ir–Sn–Ir close to 60°." @default.
• W1798356176 created "2016-06-24" @default.
• W1798356176 creator A5010797072 @default.
• W1798356176 creator A5018001856 @default.
• W1798356176 creator A5036698991 @default.
• W1798356176 creator A5038013421 @default.
• W1798356176 creator A5039841915 @default.
• W1798356176 creator A5057542535 @default.
• W1798356176 date "2003-01-01" @default.
• W1798356176 modified "2023-10-16" @default.
• W1798356176 title "A coordinatively flexible ligand for carbonyl clusters: bridging and terminal SnCl₃groups in the iridium clusters [Ir₄(CO)₁₁(μ-SnCl₃)]⁻, [Ir₄(CO)₁₀(SnCl₃)(μ-SnCl₃)]²⁻and [Ir₆(CO)₁₅(μ₃-SnCl₃)]⁻" @default.
• W1798356176 cites W1601292202 @default.
• W1798356176 cites W1964016830 @default.
• W1798356176 cites W1972183365 @default.
• W1798356176 cites W1972942792 @default.
• W1798356176 cites W1989672199 @default.
• W1798356176 cites W2030294193 @default.
• W1798356176 cites W2037737103 @default.
• W1798356176 cites W2042020592 @default.
• W1798356176 cites W2052116333 @default.
• W1798356176 cites W2056948376 @default.
• W1798356176 cites W2057723684 @default.
• W1798356176 cites W2060383232 @default.
• W1798356176 cites W2070435386 @default.
• W1798356176 cites W2071407902 @default.
• W1798356176 cites W2074565599 @default.
• W1798356176 cites W2076111966 @default.
• W1798356176 cites W2089085765 @default.
• W1798356176 cites W2330943160 @default.
• W1798356176 cites W269152472 @default.
• W1798356176 cites W2949120873 @default.
• W1798356176 doi "https://doi.org/10.1039/b310790f" @default.
• W1798356176 hasPublicationYear "2003" @default.
• W1798356176 type Work @default.
• W1798356176 sameAs 1798356176 @default.
• W1798356176 citedByCount "15" @default.
• W1798356176 countsByYear W17983561762013 @default.
• W1798356176 countsByYear W17983561762014 @default.
• W1798356176 countsByYear W17983561762015 @default.
• W1798356176 countsByYear W17983561762016 @default.
• W1798356176 countsByYear W17983561762022 @default.
• W1798356176 crossrefType "journal-article" @default.
• W1798356176 hasAuthorship W1798356176A5010797072 @default.
• W1798356176 hasAuthorship W1798356176A5018001856 @default.
• W1798356176 hasAuthorship W1798356176A5036698991 @default.
• W1798356176 hasAuthorship W1798356176A5038013421 @default.
• W1798356176 hasAuthorship W1798356176A5039841915 @default.
• W1798356176 hasAuthorship W1798356176A5057542535 @default.
• W1798356176 hasConcept C111185830 @default.
• W1798356176 hasConcept C115624301 @default.
• W1798356176 hasConcept C116569031 @default.
• W1798356176 hasConcept C155647269 @default.
• W1798356176 hasConcept C155860418 @default.
• W1798356176 hasConcept C161790260 @default.
• W1798356176 hasConcept C164866538 @default.
• W1798356176 hasConcept C170493617 @default.
• W1798356176 hasConcept C178790620 @default.
• W1798356176 hasConcept C185592680 @default.
• W1798356176 hasConcept C188027245 @default.
• W1798356176 hasConcept C196099240 @default.
• W1798356176 hasConcept C199360897 @default.
• W1798356176 hasConcept C2781083472 @default.
• W1798356176 hasConcept C41008148 @default.
• W1798356176 hasConcept C525849907 @default.
• W1798356176 hasConcept C528581852 @default.
• W1798356176 hasConcept C544153396 @default.
• W1798356176 hasConcept C55493867 @default.
• W1798356176 hasConcept C68381374 @default.
• W1798356176 hasConcept C71240020 @default.
• W1798356176 hasConcept C8010536 @default.
• W1798356176 hasConceptScore W1798356176C111185830 @default.
• W1798356176 hasConceptScore W1798356176C115624301 @default.
• W1798356176 hasConceptScore W1798356176C116569031 @default.
• W1798356176 hasConceptScore W1798356176C155647269 @default.
• W1798356176 hasConceptScore W1798356176C155860418 @default.
• W1798356176 hasConceptScore W1798356176C161790260 @default.
• W1798356176 hasConceptScore W1798356176C164866538 @default.
• W1798356176 hasConceptScore W1798356176C170493617 @default.
• W1798356176 hasConceptScore W1798356176C178790620 @default.
• W1798356176 hasConceptScore W1798356176C185592680 @default.
• W1798356176 hasConceptScore W1798356176C188027245 @default.
• W1798356176 hasConceptScore W1798356176C196099240 @default.
• W1798356176 hasConceptScore W1798356176C199360897 @default.
• W1798356176 hasConceptScore W1798356176C2781083472 @default.
• W1798356176 hasConceptScore W1798356176C41008148 @default.
• W1798356176 hasConceptScore W1798356176C525849907 @default.
• W1798356176 hasConceptScore W1798356176C528581852 @default.
• W1798356176 hasConceptScore W1798356176C544153396 @default.
• W1798356176 hasConceptScore W1798356176C55493867 @default.
• W1798356176 hasConceptScore W1798356176C68381374 @default.
• W1798356176 hasConceptScore W1798356176C71240020 @default.
• W1798356176 hasConceptScore W1798356176C8010536 @default.
• W1798356176 hasIssue "24" @default.
• W1798356176 hasLocation W17983561761 @default.
• W1798356176 hasOpenAccess W1798356176 @default.
• W1798356176 hasPrimaryLocation W17983561761 @default.
• W1798356176 hasRelatedWork W1975494321 @default.
• W1798356176 hasRelatedWork W1977105086 @default.

• next