Matches in SemOpenAlex for { <https://semopenalex.org/work/W1798407657> ?p ?o ?g. }
- W1798407657 endingPage "10489" @default.
- W1798407657 startingPage "10483" @default.
- W1798407657 abstract "A new thiocyanic acid-free ruthenium sensitizer, CYC-B29, containing two unsymmetrical ancillary ligands, was synthesized, and its three diastereoisomers CYC-B29-CC, CYC-B29-TT, and CYC-B29-CT with significantly different optical, electronic, and electrochemical properties were carefully separated. CYC-B29-TT with the smallest size has the strongest absorption coefficient of the MLCT band, the shortest λmax, the lowest highest occupied molecular orbital level and the highest dye loading. Therefore, dye-sensitized solar cell based on CYC-B29-TT has the highest efficiency, which is two times higher than that of CYC-B29-CC-sensitized device and 10% higher than that of N719-based cell. Time-dependent density functional theory-calculated transition bands for the three isomers are not identical, and only CYC-B29-TT has the calculated transition bands close to the experimental absorption profile. Although the calculated transition bands for CYC-B29-CC and CYC-B29-CT are not consistent with the experimental data, the ground-state vertical excitation energy with oscillator strength and electron-density difference map data combining with the dye loading predict correctly the order of the photocurrent for the three isomers sensitized devices." @default.
- W1798407657 created "2016-06-24" @default.
- W1798407657 creator A5003178040 @default.
- W1798407657 creator A5022864013 @default.
- W1798407657 creator A5031477633 @default.
- W1798407657 creator A5049894459 @default.
- W1798407657 creator A5063640715 @default.
- W1798407657 creator A5079624088 @default.
- W1798407657 date "2015-10-19" @default.
- W1798407657 modified "2023-09-25" @default.
- W1798407657 title "Diastereoisomers of Ruthenium Dyes with Unsymmetric Ligands for DSC: Fundamental Chemistry and Photovoltaic Performance" @default.
- W1798407657 cites W1966750682 @default.
- W1798407657 cites W1971017425 @default.
- W1798407657 cites W1972355429 @default.
- W1798407657 cites W1973209830 @default.
- W1798407657 cites W1980216394 @default.
- W1798407657 cites W1987090194 @default.
- W1798407657 cites W1990605079 @default.
- W1798407657 cites W1996858015 @default.
- W1798407657 cites W1999862775 @default.
- W1798407657 cites W2002828452 @default.
- W1798407657 cites W2021535801 @default.
- W1798407657 cites W2022122808 @default.
- W1798407657 cites W2026248210 @default.
- W1798407657 cites W2036431718 @default.
- W1798407657 cites W2043439061 @default.
- W1798407657 cites W2052428005 @default.
- W1798407657 cites W2054878825 @default.
- W1798407657 cites W2055316964 @default.
- W1798407657 cites W2061497891 @default.
- W1798407657 cites W2067881779 @default.
- W1798407657 cites W2070833739 @default.
- W1798407657 cites W2073110656 @default.
- W1798407657 cites W2076437506 @default.
- W1798407657 cites W2080518674 @default.
- W1798407657 cites W2081049288 @default.
- W1798407657 cites W2088288741 @default.
- W1798407657 cites W2088579234 @default.
- W1798407657 cites W2096651185 @default.
- W1798407657 cites W2109767338 @default.
- W1798407657 cites W2114384442 @default.
- W1798407657 cites W2116327492 @default.
- W1798407657 cites W2120517672 @default.
- W1798407657 cites W2121304740 @default.
- W1798407657 cites W2123067320 @default.
- W1798407657 cites W2145378258 @default.
- W1798407657 cites W2148332417 @default.
- W1798407657 cites W2156328797 @default.
- W1798407657 cites W2157473683 @default.
- W1798407657 cites W2335749130 @default.
- W1798407657 cites W4232616197 @default.
- W1798407657 cites W4376849569 @default.
- W1798407657 doi "https://doi.org/10.1021/acs.inorgchem.5b01967" @default.
- W1798407657 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26479183" @default.
- W1798407657 hasPublicationYear "2015" @default.
- W1798407657 type Work @default.
- W1798407657 sameAs 1798407657 @default.
- W1798407657 citedByCount "17" @default.
- W1798407657 countsByYear W17984076572016 @default.
- W1798407657 countsByYear W17984076572017 @default.
- W1798407657 countsByYear W17984076572018 @default.
- W1798407657 countsByYear W17984076572019 @default.
- W1798407657 countsByYear W17984076572020 @default.
- W1798407657 countsByYear W17984076572021 @default.
- W1798407657 countsByYear W17984076572023 @default.
- W1798407657 crossrefType "journal-article" @default.
- W1798407657 hasAuthorship W1798407657A5003178040 @default.
- W1798407657 hasAuthorship W1798407657A5022864013 @default.
- W1798407657 hasAuthorship W1798407657A5031477633 @default.
- W1798407657 hasAuthorship W1798407657A5049894459 @default.
- W1798407657 hasAuthorship W1798407657A5063640715 @default.
- W1798407657 hasAuthorship W1798407657A5079624088 @default.
- W1798407657 hasConcept C120665830 @default.
- W1798407657 hasConcept C121332964 @default.
- W1798407657 hasConcept C125287762 @default.
- W1798407657 hasConcept C1276947 @default.
- W1798407657 hasConcept C138716334 @default.
- W1798407657 hasConcept C147597530 @default.
- W1798407657 hasConcept C147789679 @default.
- W1798407657 hasConcept C152365726 @default.
- W1798407657 hasConcept C161790260 @default.
- W1798407657 hasConcept C17525397 @default.
- W1798407657 hasConcept C178790620 @default.
- W1798407657 hasConcept C185592680 @default.
- W1798407657 hasConcept C2779845233 @default.
- W1798407657 hasConcept C2780824857 @default.
- W1798407657 hasConcept C4839761 @default.
- W1798407657 hasConcept C48421929 @default.
- W1798407657 hasConcept C49040817 @default.
- W1798407657 hasConcept C555196967 @default.
- W1798407657 hasConcept C68801617 @default.
- W1798407657 hasConcept C71240020 @default.
- W1798407657 hasConcept C99191460 @default.
- W1798407657 hasConceptScore W1798407657C120665830 @default.
- W1798407657 hasConceptScore W1798407657C121332964 @default.
- W1798407657 hasConceptScore W1798407657C125287762 @default.
- W1798407657 hasConceptScore W1798407657C1276947 @default.
- W1798407657 hasConceptScore W1798407657C138716334 @default.