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- W1798929768 abstract "Ruthenium nanoparticles (Ru-NPs) can be deposited on thermally reduced graphite oxide (TRGO) in propylene carbonate (PC). Propylene carbonate is a biodegradable and non-toxic solvent. Synthesis of Ru-NPs and deposition on TRGO were achieved by decomposition of ruthenium dodecacarbonyl, Ru3(CO)12, by microwave irradiation. [email protected] nanomaterials were identified and characterized by high resolution transmission electron microscopy (TEM, HR-TEM), energy-dispersive X-ray diffraction (EDX), selected area electron diffraction (SAED), X-ray photoelectron spectroscopy (XPS) and powder X-ray diffraction (PXRD) with a small diameter and size distribution of 7±4nm Ru-NPs on TRGO. These [email protected] nanomaterials are active catalysts for the solvent-free hydrogenation of benzene to cyclohexane under mild conditions (100 °C, 10 bar) with activities of 34,000(molcyclohexane)⋅(molRu)−1⋅h−1 and over 90% conversion in at least ten consecutive runs." @default.
- W1798929768 created "2016-06-24" @default.
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- W1798929768 date "2015-08-01" @default.
- W1798929768 modified "2023-10-16" @default.
- W1798929768 title "Synthesis of ruthenium@graphene nanomaterials in propylene carbonate as re-usable catalysts for the solvent-free hydrogenation of benzene" @default.
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- W1798929768 doi "https://doi.org/10.1016/j.nanoso.2015.07.002" @default.
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