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• W179918040 abstract "We studied the association between hydrophobically modified poly(sodium acrylate) (HMPA) and nonionic surfactants of the oligoethylene glycol monododecyl ether type (mainly C12E8 and C12E4). The HMPA contains octadecyl chains randomly anchored on 1 or 3 mol% of the monomer units. The association has a large impact on the phase behavior and the rheological properties of the aqueous HMPA/nonionic surfactant mixtures.Small amounts of HMPA dramatically increase the stability of micellar and lamellar phases of C12E4. In the presence of C12E8 small mixed micelles are formed, including the alkyl side chains of the polymer, acting as crosslinks between the polymer chaisn. On the other hand, C12E4 forms giant vesicle aggregates (above 23 °C) on the surface of which the polymer is adsorbed forming bridges between adjacent vesicles. By utilizing the intrinsic phase behavior of water/nonionic surfactant system, thermal gelation can be induced in the presence of polymer at the temperature corresponding to the formation of bilayers in the binary surfactant/water system." @default.
• W179918040 created "2016-06-24" @default.
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• W179918040 date "2007-12-10" @default.
• W179918040 modified "2023-09-25" @default.
• W179918040 title "Association between hydrophobic polyelectrolytes and nonionic surfactants. Phase behavior and rheology" @default.
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• W179918040 doi "https://doi.org/10.1007/bfb0115205" @default.
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