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- W1799989938 abstract "Abstract The hydrogen bonding ligand, 3-NH(t-butyl)-5-methyl-pyrazole, forms “scorpionate-like” first row transition metal complexes that are held together by hydrogen bonds rather than covalent bonds. The formulae of these complexes are (LH)nMX2, where n = 3, 4; X = Cl, Br; and LH = 3-NH(t-butyl)-5-methyl-pyrazole. The amino-substituted pyrazole can hydrogen bond via both the amino group and the pyrazole NH to form intramolecular NH to halide hydrogen bonds. These complexes have been well characterized and show a 3:1 ratio of ligand to metal for zinc and cobalt (1 and 2), and a 4:1 ratio of ligand to metal for manganese and nickel (3 and 4). The hydrogen bonding interactions appear to be stronger for the 3:1 complexes. The crystallographic and spectroscopic studies (EPR and NMR) have shown that these hydrogen-bonding interactions are strong enough to perturb metal halogen bond distances and, with non-hydrogen bonding solvents, the hydrogen bonds appear to hold these complexes together in solution." @default.
- W1799989938 created "2016-06-24" @default.
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- W1799989938 date "2016-08-01" @default.
- W1799989938 modified "2023-10-17" @default.
- W1799989938 title "“Scorpionate-like” complexes that are held together by hydrogen bonds: Crystallographic and spectroscopic studies of (3-NH(t-butyl)-5-methyl-pyrazole) MX2 (M = Zn, Ni, Co, Mn; n= 3, 4; X = Cl, Br)" @default.
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- W1799989938 doi "https://doi.org/10.1016/j.poly.2015.10.003" @default.
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