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- W1808258118 abstract "The Cu(I) complex [Me 2 Ga(OCH 2 CH 2 NMe 2 )N 2 C 5 H 7 ]Cu•PPh 3 has been synthesized and its fluxional behavior in solution probed. Attempts have been made to isolate the analogous Cu(I) carbonyl complex. Crystals of [dimethyl(3,5-dimethyl-1-pyrazolyl)(N,N-dimethylethanolamino)gallato (N(2),O,N(3))](triphenylphosphine)copper(I) are monoclinic, a = 18.871(2), b = 9.464(1), c = 18.374(2) Ā, β = 109.62(1)°, Z = 4, space group P2 1 /c. The structure was solved by direct methods and was refined by full-matrix least-squares procedures to R = 0.028 and R w = 0.035 for 2729 reflections with I ≥ 3σ(I). The copper atom is bonded to the phosphine and to the tridentate Me 2 Ga(OCH 2 CH 2 NMe 2 )N 2 C 5 H 7 − ligand resulting in a distorted tetrahedral coordination geometry. The Cu—P distance of 2.156(1) Å is unusually short. Other important bond distances (corrected for libration) are: Cu—O, 2.163(2), Cu—N(pyrazolyl), 2.025(3), Cu—N(amino), 2.144(3), Ga—O, 1.896(3), Ga—N, 2.005(3), and Ga—C, 1.972(5) and 1.987(5) Å." @default.
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- W1808258118 date "1981-02-01" @default.
- W1808258118 modified "2023-09-28" @default.
- W1808258118 title "Synthesis, characterization, and X-ray structural analysis of the Cu(I) derivative, [Me<sub>2</sub>Ga(OCH<sub>2</sub>CH<sub>2</sub>NMe<sub>2</sub>)N<sub>2</sub>C<sub>5</sub>H<sub>7</sub>]Cu• PPh<sub>3</sub>" @default.
- W1808258118 doi "https://doi.org/10.1139/v81-072" @default.
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