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- W1811151156 abstract "We investigate the structure formation of amphiphilic molecules at planar walls using density functional theory. The molecules are modeled as (hard) spheres composed of a hydrophilic and hydrophobic part. The orientation of the resulting Janus particles is described as a vector representing an internal degree of freedom. Our density functional approach involves fundamental measure theory combined with a mean-field approximation for the anisotropic interaction. Considering neutral, hydrophilic, and hydrophobic walls, we study the adsorption of the particles, focusing on the competition between the surface field and the interaction-induced ordering phenomena. Finally, we consider systems confined between two planar walls. It is shown that the anisotropic Janus interaction yields pronounced frustration effects at low temperatures." @default.
- W1811151156 created "2016-06-24" @default.
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- W1811151156 date "2011-04-21" @default.
- W1811151156 modified "2023-09-30" @default.
- W1811151156 title "Ordering of amphiphilic Janus particles at planar walls: A density functional study" @default.
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- W1811151156 doi "https://doi.org/10.1063/1.3579453" @default.
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