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• W1811646208 endingPage "8938" @default.
• W1811646208 startingPage "8926" @default.
• W1811646208 abstract "Tuning of ligand properties is at the heart of influencing chemical reactivity and generating tailor-made catalysts. Herein, three series of complexes [Ru(L)(Cl)(X)]PF6 (X=DMSO, PPh3 , or CD3 CN) with tripodal ligands (L1-L5) containing pyridine and triazole arms are presented. Triazole-for-pyridine substitution and the substituent at the triazole systematically influence the redox behavior and photoreactivity of the complexes. The mechanism of the light-driven ligand exchange of the DMSO complexes in CD3 CN could be elucidated, and two seven-coordinate intermediates were identified. Finally, tuning of the ligand framework was applied to the catalytic oxygenation of alkanes, for which the DMSO complexes were the best catalysts and the yield improved with increasing number of triazole arms. These results thus show how click-derived ligands can be tuned on demand for catalytic processes." @default.
• W1811646208 created "2016-06-24" @default.
• W1811646208 creator A5002175536 @default.
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• W1811646208 creator A5075219696 @default.
• W1811646208 creator A5089173070 @default.
• W1811646208 date "2015-05-08" @default.
• W1811646208 modified "2023-10-16" @default.
• W1811646208 title "Tailoring Ru^IIPyridine/Triazole Oxygenation Catalysts and Using Photoreactivity to Probe their Electronic Properties" @default.
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• W1811646208 doi "https://doi.org/10.1002/chem.201406441" @default.
• W1811646208 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25960319" @default.
• W1811646208 hasPublicationYear "2015" @default.
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