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- W1818797986 abstract "The synthesis of a series of extremely bulky secondary amines with a phosphine function, Ar<sup>†</sup>(PR<sub>2</sub>)NH (Ar<sup>†</sup>= C<sub>6</sub>H<sub>2</sub>{C(H)Ph<sub>2</sub>}<sub>2</sub>Pr<sup>i</sup>-2,6,4; R = Ph, NEt<sub>2</sub>, NPr<sup>i</sup><sub>2</sub>) is described. Deprotonation with either<italic>n</italic>-BuLi or KH yields the respective alkali metal amides. Reactions with a series of chlorosilanes allows access to monomeric molecular compounds bearing the extremely bulky amino substituents<italic>via</italic>salt elimination." @default.
- W1818797986 created "2016-06-24" @default.
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- W1818797986 date "2015-01-01" @default.
- W1818797986 modified "2023-09-24" @default.
- W1818797986 title "Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes" @default.
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- W1818797986 doi "https://doi.org/10.1039/c5dt02504d" @default.
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