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- W181949340 abstract "The interactions of the complexes Mn(PPhMe2)Br/sub 2/ and Mn(PEt3)Br/sub 2/ as films with SO/sub 2/ were investigated using infrared spectroscopy as an analytical probe. It is clear from these preliminary studies that two types of complexes with SO/sub 2/ have been formed. When the MnLBr/sub 2/ films were exposed to low pressures of SO/sub 2/ for relatively short times, an MnLBr/sub 2//SO/sub 2/ complex formed reversibly in that the SO/sub 2/ could be removed by prolonged evacuation. On the other hand, lengthy exposure of the MnLBr/sub 2/ films to higher pressures of SO/sub 2/ caused the irreversible formation of a complex having stoichiometry MnLBr/sub 2/.1/2 SO/sub 2/. It is probable tht the SO/sub 2/ bonds in some type of bridging fashion in both of the types of MnLBr/sub 2//SO/sub 2/ complexes." @default.
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- W181949340 date "1985-07-18" @default.
- W181949340 modified "2023-09-27" @default.
- W181949340 title "Interaction of complexes Mn(PPhMe2)Br2 and mn(PET3)Br2 with sulfur dioxide. Technical report" @default.
- W181949340 hasPublicationYear "1985" @default.
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