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- W1822224619 endingPage "3744" @default.
- W1822224619 startingPage "3737" @default.
- W1822224619 abstract "A new route from benzylic imines permits the synthesis of 1,2-borazaronaphthalenes in good yields. The reaction involves formation of the enamidyl dibromoborane, which undergoes base-promoted borylation of the nearby aromatic C-H bond. Electrophilic attack of the boron species onto the benzylic arene is supported by the slow borylation of arenes substituted with electron-withdrawing groups. The resultant boron bromides can be easily substituted with lithium reagents to provide a range of products. The electronic properties of these 1,2-borazaronaphthalene derivatives have been investigated by UV-vis and fluorescence spectroscopy." @default.
- W1822224619 created "2016-06-24" @default.
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- W1822224619 creator A5079798449 @default.
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- W1822224619 date "2015-02-27" @default.
- W1822224619 modified "2023-10-15" @default.
- W1822224619 title "Synthesis of 1,2-Borazaronaphthalenes from Imines by Base-Promoted Borylation of C–H bond" @default.
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- W1822224619 doi "https://doi.org/10.1021/jo5029437" @default.
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