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• W1823683481 abstract "ABSTRACT Eu(NO 3 ) 3 ⋅5H 2 O and EuCl 3 ⋅6H 2 O were allowed to react with bis(diphenylphosphino)alkane dioxides Ph 2 P(O)(CH 2 ) n P(O)Ph 2 ( n = 2, 4, 6) to obtain polymeric and binuclear complexes. The prepared compounds were structurally characterized by X‐ray diffraction. Luminescence measurements (emission and excitation spectra, quantum yields, lifetimes) were compared with crystallographic data in order to find a relationship between luminescent properties of the Eu(III) complexes and their structures. The Eu(III) polymers, especially [Eu(dpphO 2 ) 2 Cl 2 ] + Cl – } n , have shown extremely long luminescence lifetimes, up to 3.73 ms, as a result of a highly protecting hydrophobic shield. Copyright © 2011 John Wiley & Sons, Ltd." @default.
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• W1823683481 date "2011-04-13" @default.
• W1823683481 modified "2023-10-15" @default.
• W1823683481 title "Luminescent properties of europium complexes with bis(diphenylphosphino)alkane dioxides" @default.
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• W1823683481 doi "https://doi.org/10.1002/bio.1291" @default.
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