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- W1824403848 endingPage "2137" @default.
- W1824403848 startingPage "2130" @default.
- W1824403848 abstract "The di-tert-butylphosphido-boratabenzene ligand (DTBB) reacts with [(C2H4)2RhCl]2 yielding the dimeric species [(C2H4)Rh(DTBB)]2 (1). This species was fully characterized by multinuclear NMR and X-ray crystallography. Complex 1 readily dissociates ethylene in solution and upon exposure to 1 atm of H2 is capable of carrying out the hydrogenation of ethylene. The characterization of two Rh-H species by multinuclear NMR spectroscopy is provided. The reactivity of 1 towards the catalytic hydrogenation of alkenes and alkynes at room temperature and 1 atm of H2 is reported and compared to the activity of Wilkinson's catalyst under the same reaction conditions." @default.
- W1824403848 created "2016-06-24" @default.
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- W1824403848 date "2016-01-01" @default.
- W1824403848 modified "2023-10-11" @default.
- W1824403848 title "Phosphidoboratabenzene–rhodium(<scp>i</scp>) complexes as precatalysts for the hydrogenation of alkenes at room temperature and atmospheric pressure" @default.
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- W1824403848 doi "https://doi.org/10.1039/c5dt03109e" @default.
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- W1824403848 hasPublicationYear "2016" @default.
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