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• W182918312 abstract "The effect of structure on the rates of hydrogenations catalyzed by Pt, Pd, and Ni is compared with the effects upon the rates of reduction by diimide (diazene) (Garbisch) and the association constants with a Ni(0) complex (Tolman). These later reactions serve as models for the effect of structure on certain of the elementary reactions of catalysis by metals. Some of the factors which determine the selectivity of a catalyst are reviewed including the kinetics, the metal, and the importance of isomerization as a competing reaction." @default.
• W182918312 created "2016-06-24" @default.
• W182918312 creator A5022424367 @default.
• W182918312 date "1991-01-01" @default.
• W182918312 modified "2023-09-27" @default.
• W182918312 title "Structure-Reactivity in the Hydrogenation of Alkenes. Comparisons with Reductions by Diimide and The Formation of a Ni(0) Complex" @default.
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• W182918312 doi "https://doi.org/10.1016/s0167-2991(08)61105-2" @default.
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