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• W1830572570 abstract "The electronic properties of the ferroelectric compound ${mathrm{Sn}}_{2}{mathrm{P}}_{2}{mathrm{S}}_{6}$ are investigated by x-ray photoelectron spectroscopy and soft x-ray fluorescence spectroscopy. Excellent agreement between theoretical calculations and experimental data for the electronic structure of the investigated compound is achieved. With help of the Sn core level spectra it is confirmed that the compound contains ${mathrm{Sn}}^{2+}$ ions. The valence band mainly consists of five resolvable bands between 3.3 eV and 14.5 eV. Consistent with the results of band-structure calculation and the soft x-ray fluorescence spectra, ${mathrm{Sn}}_{2}{mathrm{P}}_{2}{mathrm{S}}_{6}$ can be viewed as an ionic crystal, built of ${mathrm{Sn}}^{2+}$ and the $({mathrm{P}}_{2}{mathrm{S}}_{6}{)}^{4ensuremath{-}}$ fragments. Within the latter, P-P and P-S bonds are largely covalent and characterized by $mathrm{sp}$ hybridization." @default.
• W1830572570 created "2016-06-24" @default.
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• W1830572570 date "2003-03-03" @default.
• W1830572570 modified "2023-09-27" @default.
• W1830572570 title "Electronic structure of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Sn</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>P</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>S</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow…" @default.
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• W1830572570 doi "https://doi.org/10.1103/physrevb.67.115101" @default.
• W1830572570 hasPublicationYear "2003" @default.
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