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• W1830991476 abstract "The reactivity of a PNP cobalt(I) complex towards the nitrous oxide N-heterocyclic carbene adduct (NHC–N2O) was explored. Several products were isolated including the cobalt nitrosyl complex (HPNP)Co(NO) (1) and the NHC-derived imine NHCNH (2). This study provides a rare example of metal-mediated rupture of the N–N bond in a nitrous oxide derivative, a route that could be used to generate late-metal nitrosyls." @default.
• W1830991476 created "2016-06-24" @default.
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• W1830991476 date "2016-01-01" @default.
• W1830991476 modified "2023-10-12" @default.
• W1830991476 title "N–N bond cleavage in a nitrous oxide–NHC adduct promoted by a PNP pincer cobalt(I) complex" @default.
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• W1830991476 doi "https://doi.org/10.1016/j.poly.2015.09.001" @default.
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