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- W1832237150 abstract "Abstract The synthesis, characterization, magnetic properties, and magnetostructural correlation of a square‐grid complex having the molecular formula [Cu 16 L 1 8 ](dmf) 3 ( 1 ) {H 4 L 1 = 2,6‐bis[(3‐methoxysalicylidene)hydrazinecarbonyl]pyridine} is described. Reaction of the H 4 L 1 ligand and the Cu 2+ salt generates complex 1 , which exhibits a rare grid structure with a [4×4] metallic core of Cu 2+ . Structural studies revealed a mixed coordination geometry around the Cu 2+ core. The molecule has a fourfold rotational axis and one inversion center. Magnetic investigations showed the coexistence of both ferro‐ and antiferromagnetic spin exchanges, though antiferromagnetic exchange dominates over ferromagnetic coupling in the low‐temperature region." @default.
- W1832237150 created "2016-06-24" @default.
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- W1832237150 date "2014-01-28" @default.
- W1832237150 modified "2023-10-10" @default.
- W1832237150 title "Formation of a Magnetically Coupled Neutral [4×4] Square Grid from a 2,6‐Pyridinedicarbaldehyde Bis(hydrazone) Ligand" @default.
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- W1832237150 doi "https://doi.org/10.1002/ejic.201301536" @default.
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