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- W1832414085 abstract "Abstract A phosphinic amide is introduced as a directing group for the ortho C−H alkenylation of anilines. The new donor group distinguishes itself from existing ones by assisting the C−H bond activation of anilides without (NH group) and with alkylation (NMe group) at the amide nitrogen atom. The reactivity is even reversed with the methyl‐substituted anilide being more reactive than its unsubstituted counterpart. Electron‐donating substituents at the arene ring enhance their reactivity while halogenation is not tolerated. The phosphinic amide also enables the C‐7‐selective C−H alkenylation of indoline." @default.
- W1832414085 created "2016-06-24" @default.
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- W1832414085 date "2015-09-24" @default.
- W1832414085 modified "2023-10-15" @default.
- W1832414085 title "Phosphinic Amide as Directing Group Enabling Palladium(II)-Catalyzed<i>ortho</i>C−H Alkenylation of Anilines without and with Alkylation at the Nitrogen Atom" @default.
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- W1832414085 doi "https://doi.org/10.1002/asia.201500829" @default.
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