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• W1832666439 startingPage "11826" @default.
• W1832666439 abstract "TiCl3 and NH3 form octaammine titanium(III) chloride ammonia (1/6), [Ti(NH3)8]Cl3·6NH3, which is the first structurally characterized octaammine complex of a transition metal. An excess of TiCl3 reacts with UF4 in liquid NH3 and forms octaammine fluorido uranium(IV) chloride ammonia (1/3.5), [UF(NH3)8]Cl3·3.5NH3. It shows a distorted threefold-capped trigonal-prismatic coordination sphere around U(IV)." @default.
• W1832666439 created "2016-06-24" @default.
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• W1832666439 date "2015-01-01" @default.
• W1832666439 modified "2023-10-17" @default.
• W1832666439 title "The reactions of TiCl₃, and of UF₄with TiCl₃in liquid ammonia: unusual coordination spheres in [Ti(NH₃)₈]Cl₃·6NH₃and [UF(NH₃)₈]Cl₃·3.5NH₃" @default.
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• W1832666439 doi "https://doi.org/10.1039/c5cc04411a" @default.
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• W1832666439 hasPublicationYear "2015" @default.
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