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- W1835567046 abstract "The aggregation of heterotactic-like poly(methyl methacrylate) (PMMA) in some solutions was proved by NMR spectroscopy. It was found that the fraction of aggregated units depends on solvent, solution concentration and temperature; the aggregates are completely decomposed at 45°C. Aggregation occurs by intermolecular interactions of m-diads with rrr-tetrads, i. e. by interactions of the stereocomplex type. The formation of a stable aggregated structure is probably a consequence of the microstructure of the heterotactic-like PMMA chain, with relatively long sequences of regularly repeating mrrr pentads or mrrr hexads. The aggregation in mixtures of heterotactic-like PMMA solutions with isotactic or syndiotactic PMMA solutions was also studied." @default.
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- W1835567046 date "1987-04-01" @default.
- W1835567046 modified "2023-10-16" @default.
- W1835567046 doi "https://doi.org/10.1002/macp.1987.021880420" @default.
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