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• W1837863733 abstract "Abstract If the distance between atoms in a crystalline lattice is increased, an energy gap appears, which in a divalent material will separate occupied from unoccupied states of an electron. In a non-crystalline substance, a minimum is expected in the density of states (a ‘pseudogap’). An approximate theoretical estimate is given of the depth of the minimum at which the one-electron states become localized so that 〈σE(0)〉 vanishes; this turns out to be such that N(E F)/N(E F)free is about ⅓. The result depends rather sensitively on the parameters used; the value deduced from the experiments of Hensel and Franck (1966, 1968) on the resistivity of mercury at high temperatures gives for this ratio a value of ⅕. It is shown also that the localized states at the extremities of a valence or conduction band are of negligible importance if the wave functions are s-like on the atoms or ions, but may be of importance if they are not. A discussion is given of the electrical behaviour of chalcogenide glasses, amorphous germanium and of some liquid semiconductors based on these ideas." @default.
• W1837863733 created "2016-06-24" @default.
• W1837863733 creator A5007765278 @default.
• W1837863733 date "1969-04-01" @default.
• W1837863733 modified "2023-10-14" @default.
• W1837863733 title "Conduction in non-crystalline materials" @default.
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• W1837863733 doi "https://doi.org/10.1080/14786436908216338" @default.
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