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• W1838038158 abstract "The photoluminescence and temperature sensing properties based on down-shifting emission of Pr3+-doped (K0.5Na0.5)NbO3–yCaTiO3 (KNN: yCT) diphasic materials were systematically investigated. Under 447-nm excitation, Pr3+-doped KNN: yCT samples exhibited significantly enhanced red emission at 603 nm assigned to 1D2→3H4 transitions of Pr3+ ions. The red emission intensities reached the optimum value with y = 0.05 near the polymorphic phase transition region. The origin of the enhanced red emission is mainly ascribed to the doping-induced lattice symmetry change. The energy level transitions from the typical f–f transitions to the valence-to-conduction transitions were observed as CaTiO3 concentration increases above a critical concentration of y = 0.05. Furthermore, the sample with y = 0.05 also possessed excellent temperature response properties in a wide temperature range 300–473 K and the maximum sensing sensitivity was 0.016 K−1. The Pr3+-doped (K0.5Na0.5)NbO3–yCaTiO3 red emission materials with admirable intrinsic piezoelectric properties may have important technological promise in novel multifunctional devices." @default.
• W1838038158 created "2016-06-24" @default.
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• W1838038158 date "2014-11-25" @default.
• W1838038158 modified "2023-10-15" @default.
• W1838038158 title "Strong Red Emissions in Pr³⁺ -Doped (K_0.5 Na_0.5 )NbO₃ -CaTiO₃ Diphase Ceramics" @default.
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• W1838038158 doi "https://doi.org/10.1111/jace.13362" @default.
• W1838038158 hasPublicationYear "2014" @default.
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