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• W1840945162 abstract "In this work, a novel ratiometric fluorescent probe was developed for rapid, highly accurate, sensitive and selective detection of mercury(II) (Hg(2+)) based on terbium(III)/gold nanocluster conjugates (Tb(3+)/BSA-AuNCs), in which bovine serum albumin capped gold nanoclusters (BSA-AuNCs) acted as the signal indicator and terbium(III) (Tb(3+)) was used as the build-in reference. Our proposed ratiometric fluorescent probe exhibited unique specificity toward Hg(2+) against other common environmentally and biologically important metal ions, and had high accuracy and sensitivity with a low detection limit of 1 nM. In addition, our proposed probe was effectively employed to detect Hg(2+) in the biological samples from the artificial Hg(2+)-infected rats. More significantly, an appealing paper-based visual sensor for Hg(2+) was designed by using filter paper embedded with Tb(3+)/BSA-AuNC conjugates, and we have further demonstrated its feasibility for facile fluorescent sensing of Hg(2+) in a visual format, in which only a handheld UV lamp is used. In the presence of Hg(2+), the paper-based visual sensor, illuminated by a handheld UV lamp, would undergo a distinct fluorescence color change from red to green, which can be readily observed with naked eyes even in trace Hg(2+) concentrations. The Tb(3+)/BSA-AuNC-derived paper-based visual sensor is cost-effective, portable, disposable and easy-to-use. This work unveiled a facile approach for accurate, sensitive and selective measuring of Hg(2+) with self-calibration." @default.
• W1840945162 created "2016-06-24" @default.
• W1840945162 creator A5026175186 @default.
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• W1840945162 date "2015-01-01" @default.
• W1840945162 modified "2023-09-25" @default.
• W1840945162 title "Terbium(<scp>iii</scp>)/gold nanocluster conjugates: the development of a novel ratiometric fluorescent probe for mercury(<scp>ii</scp>) and a paper-based visual sensor" @default.
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• W1840945162 doi "https://doi.org/10.1039/c5an00802f" @default.
• W1840945162 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26140286" @default.
• W1840945162 hasPublicationYear "2015" @default.
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