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- W1843485106 abstract "A photoionization-efficiency spectrum of CH3SCH2Cl was measured over the wavelength range 108–142 nm by means of a photoionization mass spectrometer coupled to a synchrotron as the source of radiation. Gaseous CH3SCH2Cl was generated in a discharge-flow reactor involving Cl, Cl2, and CH3SCH3 at room temperature via these sequential reactions: Cl+CH3SCH3→CH3SCH2+HCl; CH3SCH2+Cl2→CH3SCH2Cl+Cl. According to the PIE spectrum of CH3SCH2Cl thus obtained, the ionization energy is (9.077±0.007) eV. Based on GAUSSIAN-2 calculations, the observed ionization of CH3SCH2Cl near the threshold region is likely to form from singlet CH3SCH2Cl ionizing to doublet CH3SCH2Cl+; the calculated ionization energy 9.064 eV agrees with the experimental value. The adiabatic ionization energy of CH3SCH2 and appearance energy of CH3SCH2+ from CH3SCH2Cl were determined to be (6.884±0.008) eV and (10.007±0.016) eV, respectively; the dissociation energy of the CH3SCH2–Cl bond is thus derived to be (72.0±0.6) kcal mol−1." @default.
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- W1843485106 date "2001-03-15" @default.
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- W1843485106 title "Photoionization study of CH3SCH2Cl formed in the reaction system Cl/Cl2/CH3SCH3" @default.
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- W1843485106 doi "https://doi.org/10.1063/1.1349078" @default.
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