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- W1844290280 abstract "The expression “stiffness” of a polymer chain is shown to be ambiguous, and the use of the word “rectilinearity” is proposed to replace it in certain contexts. The influence of non-uniform curvature on Kuhn length and mean-square end-to-end distance of (co)polymers is studied using the frameworks of the freely-rotating-chain model and the Porod-Kratky model. It is shown that every fluctuation around the given mean curvature of a chain increases its overall rectilinearity. Specifically, it is concluded that the rectilinearity increases with increasing fluctuation magnitude and with increasing separation of the different curvatures along the chain, i. e., it becomes greater in the order: alternating, random and block copolymer." @default.
- W1844290280 created "2016-06-24" @default.
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- W1844290280 date "1991-08-01" @default.
- W1844290280 modified "2023-10-16" @default.
- W1844290280 doi "https://doi.org/10.1002/macp.1991.021920801" @default.
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