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- W1844697116 abstract "2-Trifluoromethyl-5-(arylsulfonyl)methyl pyrroles and 2-trifluoromethyl-4-(arylsulfonyl)methyl pyrroles were selectively synthesized from trifluoromethyl-substituted 3-aza-1,5-enynes via a cyclization/sulfonyl group migration cascade catalyzed by AgOOCCF3 and CsOPiv, respectively. Alkylvinyl-substituted pyrroles were generated from seven-atom skeleton 3-aza-1,5-enynes via aryl sulfinic acid elimination in the presence of Cs2CO3. Two ion-pair intermediates were proposed and a key intermediate, aza-diene-yne, was successfully isolated in the mechanistic studies." @default.
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- W1844697116 date "2016-01-01" @default.
- W1844697116 modified "2023-10-09" @default.
- W1844697116 title "Selective synthesis of functionalized pyrroles from 3-aza-1,5-enynes" @default.
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- W1844697116 doi "https://doi.org/10.1039/c5ob01887k" @default.
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