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- W184480013 abstract "Abstract The conversion of glycerol in aqueous solution at 513 K under 3 MPa hydrogen pressure in the presence of Ru, Ni, Rh, Ir based catalysts leads to hydrocarbons, mainly methane: these metals hydrogenolyse both C-C and C-0 bonds. Hydrogenolysis reactions are not observed with copper. Glycerol dehydrogenation and strong adsorption of dehydrogenated species on this metal lead to selective dehydroxylation (C-0 cleavage) and retro-CLAISEN (C-C cleavage) reactions. These reactions determine the nature of the products obtained from erythritol, xylitol and sorbitol conversions, but, for the two latter polyols, there is also a retro-MICHAEL reaction. This reaction yields selectively glycerol from sorbitol and is favoured on certain copper-based catalysts." @default.
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- W184480013 date "1988-01-01" @default.
- W184480013 modified "2023-10-15" @default.
- W184480013 title "Polyol Conversion by Liquid Phase Heterogeneous Catalysis Over Metals" @default.
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- W184480013 doi "https://doi.org/10.1016/s0167-2991(09)60811-9" @default.
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